trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate

The title complex, [PdCl2(C18H15P)2]·0.5C6H6, has the PdII ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh3 and Cl ligands mutually trans. The benzene solvent mol
The title complex, [PdCl2(C18H15P)2]·0.5C6H6, has the PdII ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh3 and Cl ligands mutually trans. The benzene solvent mol­ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl­phosphane)­palladium(II) 1,4-dichloro­benzene sesquisolvate [Kitano et al. (1983 [triangle]). Acta Cryst. C39, 1015–1017].
show moreshow less

Download full text files

Export metadata

  • Export Bibtex
  • Export RIS

Additional Services

    Share in Twitter Search Google Scholar
Metadaten
Author:Frank Meyer-Wegner, Hans-Wolfram Lerner, Tanja Sinke, Michael Bolte
URN:urn:nbn:de:hebis:30:3-252327
DOI:http://dx.doi.org/10.1107/S1600536812012494
ISSN:1600-5368
Pubmed Id:http://www.ncbi.nlm.nih.gov/pubmed?term=22589859
Parent Title (English):Acta crystallographica : Section E, Structure reports online
Publisher:Munksgaard
Place of publication:Copenhagen
Document Type:Article
Language:English
Year of first Publication:2012
Publishing Institution:Univ.-Bibliothek Frankfurt am Main
Release Date:2012/06/17
Volume:68
Issue:m570
Note:
Lizenz: http://journals.iucr.org/services/oa/openaccess_e.html
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung 3.0

$Rev: 11761 $