Redetermination of (acetonitrile-κN)dicarbon-yl(η(5)-cyclo-penta-dien-yl)iron(II) tetra-fluoridoborate

The crystal structure of the title compound, [Fe(C5H5)(CH3CN)(CO)2]BF4, of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 [triangle]). Z. Anorg. Allg. Chem. 
The crystal structure of the title compound, [Fe(C5H5)(CH3CN)(CO)2]BF4, of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 [triangle]). Z. Anorg. Allg. Chem. 453, 98–106] has been redetermined. The FeII atom in the complex cation is coordinated by a cyclo­penta­dienyl ring, two carbonyl ligands and an acetonitrile mol­ecule displaying a three-legged piano stool structure. Three of the four F atoms of the BF4 − anion are disordered over two sets of sites, with a site-occupancy factor of 0.709 (10) for the major occupied site.
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Metadaten
Author:Theresa Irene Kückmann, Hans-Wolfram Lerner, Michael Bolte
URN:urn:nbn:de:hebis:30:3-258600
DOI:http://dx.doi.org/10.1107/S1600536812027857
ISSN:1600-5368
Pubmed Id:http://www.ncbi.nlm.nih.gov/pubmed?term=22807785
Parent Title (English):Acta crystallographica / Section E, Structure reports online
Publisher:Munksgaard
Place of publication:Copenhagen
Document Type:Article
Language:English
Date of Publication (online):2012/06/23
Date of first Publication:2012/06/23
Publishing Institution:Univ.-Bibliothek Frankfurt am Main
Release Date:2012/08/28
Volume:68
Issue:m966
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung 3.0

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