Sodium pentafluorophenylborate
The crystal structure of the title compound, Na[(C6F5)BH3], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na...B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na...F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network. The anion is the first structural example of a pentafluorophenyl ring carrying a BH3 group.
| Author: | Hannes Vitze, Hans-Wolfram Lerner, Michael Bolte |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-274244 |
| DOI: | http://dx.doi.org/http://dx.doi.org/10.1107/S1600536812042584 |
| ISSN: | 1600-5368 |
| Parent Title (English): | Acta crystallographica / Section E, Structure reports online |
| Publisher: | Munksgaard |
| Place of publication: | Copenhagen |
| Document Type: | Article |
| Language: | English |
| Year of first Publication: | 2012 |
| Publishing Institution: | Univ.-Bibliothek Frankfurt am Main |
| Volume: | 68 |
| Issue: | m1371 |
| Institutes: | Biochemie und Chemie |
| Dewey Decimal Classification: | 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Note: | Authors will not be asked to transfer copyright to the IUCr, but will instead be asked to agree during article submission to an open-access licence. This licence is identical to the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode. |
| Licence (German): |  Creative Commons - Namensnennung 2.0 |
