Dibromidotris(dimethylamine)-magnesium(II)

The Mg centre in the title compound, [MgBr2(C2H7N)3], is pentacoordinated in a trigonal-bipyramidal mode with the two Br atoms in axial positions and the N atoms of the dimethylamine ligands in equatorial positions. The 
The Mg centre in the title compound, [MgBr2(C2H7N)3], is pentacoordinated in a trigonal-bipyramidal mode with the two Br atoms in axial positions and the N atoms of the dimethylamine ligands in equatorial positions. The MgII centre is located on a crystallographic twofold rotation axis. The crystal structure is stabilized by N-H...Br hydrogen bonds. The N atom and H atoms of one dimethylamine ligand are disordered over two equally occupied positions. Key indicators: single-crystal X-ray study; T = 173 K; mean σ(N–C) = 0.005 A° ; disorder in main residue; R factor = 0.022; wR factor = 0.049; data-to-parameter ratio = 21.1.
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Metadaten
Author:Hannes Vitze, Hans-Wolfram Lerner, Michael Bolte
URN:urn:nbn:de:hebis:30-68927
Document Type:Article
Language:English
Date of Publication (online):2009/09/02
Year of first Publication:2009
Publishing Institution:Univ.-Bibliothek Frankfurt am Main
Release Date:2009/09/02
Note:
ISSN 1600-5368 ; Copyright © International Union of Crystallography ; This licence is identical to the Creative Commons Attribution Licence. http://journals.iucr.org/services/oa/openaccess_e.html
Source:Acta Cryst. (2009). E65, m888 [ doi:10.1107/S1600536809024702 ]
HeBIS PPN:217323758
Institutes:Biochemie und Chemie
Dewey Decimal Classification:540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License Logo Veröffentlichungsvertrag für Publikationen

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