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    <title>OPUS 4 Latest Documents RSS Feed</title>
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    <pubDate>Wed, 11 Jan 2012 15:41:08 +0100</pubDate>
    <lastBuildDate>Wed, 11 Jan 2012 15:41:08 +0100</lastBuildDate>
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      <title>rac-4-Chloro-2-[({2-[(3-chloro-6-hydroxy-2,4-dimethylbenzyl)(methyl)amino]propyl}(methyl)amino)methyl]-3,5-dimethylphenol</title>
      <link>http://publikationen.stub.uni-frankfurt.de/frontdoor/index/index/docId/27429</link>
      <description>The title compound, C23H32Cl2N2O2, a potential chiral ligand for coordination chemistry, was prepared by a two-step reaction. The molecule is located on a crystallographic centre of inversion. As a result, the methyl group bonded to the methylene group is disordered over two equally occupied positions, sharing the same site as the H atom of the chiral C atom. As a further consequence of the crystallographic centrosymmetry, the 1,2-diaminopropane unit adopts an antiperiplanar conformation and the two benzene rings are coplanar. The central chain is in an all-trans arrangement. An intramolecular O-H...N hydrogen bond makes an S(6) ring motif. A C-H...[pi] interaction links the molecules into one-dimensional chains along the [001] direction.</description>
      <author>Augusto Rivera; Dency Jose Pacheco; Jaime Ríos-Motta; Mauricio Maldonado; Michael Bolte</author>
      <category>article</category>
      <guid>http://publikationen.stub.uni-frankfurt.de/frontdoor/index/index/docId/27429</guid>
      <pubDate>Thu, 01 Nov 2012 15:41:08 +0100</pubDate>
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